星期二, 九月 22, 2020
Home PV News Perovskites thrive under pressure

Perovskites thrive under pressure

Scientists in the U.S. and Nigeria have studied the effects of pressure on perovskite solar cell production and found the correct application could improve cell efficiency by as much as 40% (relative). Push them too hard though, and they crack.

Source:pv magazine

Scientists are yet to settle on the optimal fabrication method for perovskite solar cells despite a variety of candidates.

Researchers from Nigeria’s African University of Science and Technology (AUST), working with staff from Worcester Polytechnic Institute in the U.S., have suggested another novel method. Inspired by previous work on other organic thin-film solar cell materials, the group investigated the effects of pressure on perovskite cell production by using computational analysis and practical experimentation. A previous study at Brown University, in Rhode Island, showed how the correct application of stress could heal cracks in perovskite solar cells but little information is available about how pressure could be applied to production processes.

The AUST-Worcester group fabricated 85 methylammonium lead iodide perovskite solar cells using spin coating and then applied 1-10 megapascals (MPa) of pressure to them. The results, published in the paper Pressure-Assisted Fabrication of Perovskite Solar Cells, showed the application of 0-7MPa served to increase cell conversion efficiency. Beyond 7MPa, efficiency fell again as the devices suffered damage.

Results

A starting cell efficiency of 9.84% rose to 13.67% under pressures of 0-7MPa and fell to 10.89% as the pressure was increased to 10MPa. The initial increases were attributed to improved surface contacts between the cell layers and increased density of materials. Beyond 7MPa, the perovskite grain began to fragment and the layers began to sink into each other.

“The implications … are significant for the design of pressure-assisted processes that can be used for the fabrication of perovskite solar cells,” said the AUST scientists. “The significant effects of pressure suggest that pressure-assisted processes such as lamination, cold welding and rolling/roll-to-roll processing can be used to fabricate perovskite solar cells with improved performance characteristics.”

The group concluded pressures beyond 7MPa should not be considered and advised the combined effects of interlayer contact, layer compacting, infiltration and potential layer damage all be considered in the development of pressure-assisted manufacturing processes.

LEAVE A REPLY

Please enter your comment!
Please enter your name here

- Advertisment -

Most Popular

Apple data center in Denmark powered by 50 MW of solar

Apple has revealed that its data center in Viborg, Denmark, is now being powered by a 50 MW solar project under a long-term power...

Solar + storage experiment in Tampa Bay selected for Solar Energy Innovation Network project

An innovative solar + storage research project led by the Tampa Bay Regional Planning Council has been selected as a finalist for the Solar...

Chinese PV Industry Brief: 350 MW wind-solar project, 200 MW of floating PV

Longyuan Energy said this week that it has signed an agreement with the municipal authorities in Binzhou, Shandong province, to build 300 MW of solar...

IEEE creates education and credentialing program for interconnecting distributed resources to the grid

IEEE and the IEEE Standards Association (IEEE SA) announced the IEEE Std 1547-2018 Distributed Energy Resources (DER) Interconnection Commissioning: Education and Credentialing Program, a new...