星期日, 九月 27, 2020
Home PV News A pressure-assisted technique to increase perovskite solar cell efficiency

A pressure-assisted technique to increase perovskite solar cell efficiency

Researchers in the United States claim to have significantly increased the efficiency of a perovskite solar cell by applying a range of pressures to the device. According to them, pressure-assisted processes such as lamination, cold welding and rolling/roll-to-roll processing can be used to improve interfacial surface contacts in perovskite cells.

Source:pv magazine

A group of scientists at the Worcester Polytechnic Institute claims to have significantly improved the efficiency of a layered mixed halide perovskite solar cell by applying a range of pressures to the device to improve its interfacial surface contacts.

The proposed pressure-assisted manufacturing technque is said to increase pressure results in the densification of the mesoporous titanium dioxide (TiO2) layers and the infiltration of the mesoporous layers with the perovskite layers. The applied pressure results in the closing up of voids and the corresponding increase in the interfacial surface contact lengths, which increases with increasing pressure.

Mesoporous materials are a type of nanoporous materials with pores sizes between 2 and 50 nanometers which are widely used as adsorbents and catalysts. Mesoporous layers are used in perovskite cells to improve the electron transport as well as light utilization.

The solar cell efficiency was raised from 9.84% to 13.67% by applying pressure values between 0 and 7 megapascal (MPa). “However, the photoconversion efficiencies decrease with increasing pressure, for pressures beyond 7 MPa,” the scientists explained.

These lower efficiencies are due to the fragmentation of the perovskite grains, and the sink-in of the perovskite layers into the mesoporous layer. “Therefore, for best results, moderate intermediate pressures are required for improved contact,” the group stated.

The research team added that the significant effects of pressure suggest that pressure-assisted processes such as lamination, cold welding and rolling/roll-to-roll processing may be used to produce more performant perovskite solar cells.

The findings of the research were presented in the paper Pressure-Assisted Fabrication of Perovskite Solar Cells, published in Scientific Reports.

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